The coupling constant between the alkyl protons and the platinum nucleus in [Pt(C2H4)Cl2(R1R2C : N·NR3R4)] complexes is higher when the alkyl group is cis- to the metal, with respect to the azomethine double bond, than when it is trans- to it.
G. Natile, L. Maresca and L. Cattalini, J. Chem. Soc., Chem. Commun., 1976, 24 DOI: 10.1039/C39760000024
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