Ion-pairing of substituted 1,3-diphenylallyl carbanions with alkalimetal cations
Abstract
The visible absorption spectra of ether solutions of the alkali-metal salts of several substituted 1,3-diphenylpropenes are shown to correspond to the presence of tight and loose ion pairs. The enthalpy and entropy changes for the interconversion of these ion pairs have been measured for 22 combinations of anion, cation, and solvent.
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