Issue 14, 1975

Ion-pairing of substituted 1,3-diphenylallyl carbanions with alkalimetal cations

Abstract

The visible absorption spectra of ether solutions of the alkali-metal salts of several substituted 1,3-diphenylpropenes are shown to correspond to the presence of tight and loose ion pairs. The enthalpy and entropy changes for the interconversion of these ion pairs have been measured for 22 combinations of anion, cation, and solvent.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 2, 1975, 1661-1664

Ion-pairing of substituted 1,3-diphenylallyl carbanions with alkalimetal cations

G. C. Greenacre and R. N. Young, J. Chem. Soc., Perkin Trans. 2, 1975, 1661 DOI: 10.1039/P29750001661

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