Free energies of activation for inversion at nitrogen in NN′-disubstituted 1,3,4-oxadiazolidines depend markedly on the bulk of the substituents demonstrating that the steric strain of substituents eclipsed in the transition state is a dominant effect in the nitrogen inversions of substituted hydrazines.
V. J. Baker, A. R. Katritzky and J. Majoral, J. Chem. Soc., Perkin Trans. 2, 1975, 1191 DOI: 10.1039/P29750001191
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