Treatment of (E)-3-deoxy-3-C-ethoxycarbonyl(formylamino)methylene-1,2 : 5,6-di-O-isopropylidene-α-D-glucofuranose with trifluoro(fluoro-oxy)methane gives branched-chain sugars bearing a fluorine atom at the branch point. Some reactions of these fluorinated sugars are described.
K. Bischofberger, A. J. Brink and A. Jordaan, J. Chem. Soc., Perkin Trans. 1, 1975, 2457 DOI: 10.1039/P19750002457
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