4β,5β-Epoxy-6α-hydroxy- and 2α,3α-epoxy-6β-hydroxy-androstan-17β-yl acetates have been prepared. Both gave 4-methyloestratrien-17β-yl acetate on treatment with hydrobromic acid in glacial acetic acid. The former also gave 6-oxoandrost-4-en-17β-yl acetate.
D. Baldwin and J. R. Hanson, J. Chem. Soc., Perkin Trans. 1, 1975, 1107 DOI: 10.1039/P19750001107
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