β-Substituted β-methylstyrenes react with benzene in the presence of palladium(II) acetate to produce the corresponding (E)- and/or (Z)-β-substituted β-diphenylmethylstyrenes in good yields. A mechanism involving a 2-substituted 3,3-diphenylpropene intermediate is suggested. The configurations of the products are discussed.
K. Yamamura, J. Chem. Soc., Perkin Trans. 1, 1975, 988 DOI: 10.1039/P19750000988
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