Reduction of five aryltrimethylsilanes and one cyclohexenyltrimethylsilane with lithium in ethylamine gives cyclohexanes in every case. Cleavage of one carbon–silicon bond occurs in 1,3-bis(trimethylsilyl)benzene and 1,3,5-tris(trimethylsilyl)benzene. The stereochemistry of the disubstituted cyclohexanes has been assigned.
C. Eaborn, R. A. Jackson and R. Pearce, J. Chem. Soc., Perkin Trans. 1, 1975, 475 DOI: 10.1039/P19750000475
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