In determining the spectrum of adsorbed species, care must be taken either to eliminate all pre-adsorbed species, or in the interpretation of the data, since pre-adsorbed species will in general contribute to the difference spectrum of species subsequently adsorbed. Data illustrating this phenomenon, as well as a theoretical explanation of it, are presented.
B. Rao, R. W. Stobie and M. J. Dignam, J. Chem. Soc., Faraday Trans. 2, 1975, 71, 654 DOI: 10.1039/F29757100654
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