Issue 0, 1975

Nuclear quadrupole resonance and stereochemistry. Part 4.—Chlorocyclopropanes

Abstract

The 35Cl nuclear quadrupole resonance frequencies of 22 chlorocyclopropanes show that the frequencies of 1-chlorocyclopropanes are increased in a stereodependent manner by a further chlorine substituent in the 2-position, the difference between the shifts produced by cis or trans substituents being approximately 0.8 MHz. No such effect occurs for alkyl substituents.

Article information

Article type
Paper

J. Chem. Soc., Faraday Trans. 2, 1975,71, 463-467

Nuclear quadrupole resonance and stereochemistry. Part 4.—Chlorocyclopropanes

F. Delay, M. Geoffroy, E. A. C. Lucken and P. Müller, J. Chem. Soc., Faraday Trans. 2, 1975, 71, 463 DOI: 10.1039/F29757100463

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