Issue 0, 1975

Vacuum ultra-violet photolysis of nitrous oxide. Energy disposal in the reaction O(21D)+ N2O → 2NO

Abstract

The vacuum u.v. photolysis of N2O has been studied at [gt-or-equal] 170 nm, and (140–155) nm. Energy disposal in the reaction O(21D)+ N2O → 2NO has been investigated at the longer wavelengths and the distribution over vibrational states found to be consistent with a ‘complex’ mechanism. At the shorter wavelengths experiments with 15NNO indicate formation of NO via reaction of O(21D), N2(Atilde;3Σ+u) and possibly O(21S) with N2O, though the majority of O(21S) atoms are physically deactivated to the 21D state.

Article information

Article type
Paper

J. Chem. Soc., Faraday Trans. 2, 1975,71, 402-408

Vacuum ultra-violet photolysis of nitrous oxide. Energy disposal in the reaction O(21D)+ N2O → 2NO

G. A. Chamberlain and J. P. Simons, J. Chem. Soc., Faraday Trans. 2, 1975, 71, 402 DOI: 10.1039/F29757100402

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