The e.s.r. spectra of di-t-butyl nitroxide in aqueous solutions of α- or β-dextrin show that the radical complexes with the dextrin and that exchange with the aqueous environment is relatively slow. The concentration quotient for a simple association equilibrium is not constant and a simple procedure for taking account of non-ideality is suggested, and works well.
N. M. Atherton and S. J. Strach, J. Chem. Soc., Faraday Trans. 1, 1975, 71, 357 DOI: 10.1039/F19757100357
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