Issue 23, 1975
From the journal:

Journal of the Chemical Society, Dalton Transactions

Interaction of tricarbonyl(π-cyclopentadienyl)molybdenum halides and acetylenes

John L. Davidson  and  David W. A. Sharp  

Abstract

Tricarbonyl(π-cyclopentadienyl)molybdenum halides, [(cp)Mo(CO)3X](X = Cl, Br, or I), (cp =η5-C5H6) react with MeC[triple bond, length half m-dash]CMe and CF3[triple bond, length half m-dash]CCF3 to give the 16-electron bisalkyne complexes [(cp)Mo(RC2R)2X] whilst PhC[triple bond, length half m-dash]CPh gives [(cp)Mo(CO)(PhC2Ph)X] and the cyclobutadiene complexes [(cp)Mo(CO)(PhC2Ph)2X].

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Article information

DOI
https://doi.org/10.1039/DT9750002531
Article type
Paper

J. Chem. Soc., Dalton Trans., 1975, 2531-2534

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Interaction of tricarbonyl(π-cyclopentadienyl)molybdenum halides and acetylenes

J. L. Davidson and D. W. A. Sharp, J. Chem. Soc., Dalton Trans., 1975, 2531 DOI: 10.1039/DT9750002531

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