Issue 7, 1975

Cyclometallation reactions. Part 10. Some reactions of polyfluorinated azobenzenes: metallation by fluorine abstraction

Abstract

The reactions of 2,3,4,5,6-pentafluoroazobenzene and 2H-nonafluoroazobenzene with a variety of transition-metal complexes have been examined. In one case, metallation by abstraction of fluorine occurs, in addition to the usual metallation reactions found with azobenzene. The 1H and 19F n.m.r. spectra are discussed.

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1975, 591-595

Cyclometallation reactions. Part 10. Some reactions of polyfluorinated azobenzenes: metallation by fluorine abstraction

M. I. Bruce, B. L. Goodall, G. L. Sheppard and F. G. A. Stone, J. Chem. Soc., Dalton Trans., 1975, 591 DOI: 10.1039/DT9750000591

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