The preparation and properties of new high-spin five-co-ordinate and low-spin six-co-ordinate chromium(II) complexes are reported, [Cr(tdpep)X][BPh4][X = Cl, Br, or I; tdpep = tris(2-diphenylphosphinoethyl)phosphine] and [Cr(pdma)2X2][X = Cl, Br, or I; pdma =o-phenylenebis(dimethylarsine)] respectively.
F. Mani, P. Stoppioni and L. Sacconi, J. Chem. Soc., Dalton Trans., 1975, 461 DOI: 10.1039/DT9750000461
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