The ZnII-catalysed rate of formation of pyruvate dimer(parapyruvate) is enhanced by the decarboxylation of oxac2–, providing evidence for the postulated existence of intermediate pyruvate enolate in both of these reactions.
B. J. Lillis and D. L. Leussing, J. Chem. Soc., Chem. Commun., 1975, 397b DOI: 10.1039/C3975000397B
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