The reduction of Ni2+ ions in a three-dimensional matrix suggests a diffusion mechanism, whereas when the ions are contained in the lattice of an amorphous gel a germination process is involved.
M. Kermarec, M. Briend-Faure and D. Delafosse, J. Chem. Soc., Chem. Commun., 1975, 272b DOI: 10.1039/C3975000272B
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