Thermal rearrangements of hydridic (chloromethyl)silane and (chloromethyl)chlorosilane occur through an intermolecular process and not via the intra-molecular reaction of the type invoked for analogous reactions in other (halogenoalkyl) silanes.
J. M. Bellama and J. A. Morrison, J. Chem. Soc., Chem. Commun., 1975, 985 DOI: 10.1039/C39750000985
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