Issue 23, 1975

Selective hydrogenation of 4,5-dihydro-1,3-oxazin-6-ones to carboxaldehyde derivatives; chemical differentiation between acylazetidin-2-ones and the corresponding isomeric oxazin-6-ones

Abstract

The structural ambiguity between a substituted acylazetidin-2-one and the isomeric dihydrooxazin-6-one has been resolved by chemical studies; catalytic hydrogenation of the latter leads, unexpectedly, to preferential reduction of the carbonyl group to carboxaldehyde.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1975, 948-949

Selective hydrogenation of 4,5-dihydro-1,3-oxazin-6-ones to carboxaldehyde derivatives; chemical differentiation between acylazetidin-2-ones and the corresponding isomeric oxazin-6-ones

C. N. C. Drey and R. J. Ridge, J. Chem. Soc., Chem. Commun., 1975, 948 DOI: 10.1039/C39750000948

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