The catalytic effect of transition–metal–phosphine complexes on the exchange of halide between alkyl halides is shown to be due to the quaternisation of the labile phosphine ligands; the true catalyst is demonstrated to be the halide ion.
D. Forster, J. Chem. Soc., Chem. Commun., 1975, 917 DOI: 10.1039/C39750000917
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