MeMgI reacts with O-alkyl S-methyl phenylphosphonothiolates to displace either the methylthio group with retention of configuration at phosphorus or the alkoxy group with inversion, the competition depending on the nature of the alkoxy group.
K. E. Debruin and D. M. Johnson, J. Chem. Soc., Chem. Commun., 1975, 753 DOI: 10.1039/C39750000753
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