SCHEDULED MAINTENANCE
Evidence is presented that the unusual formation of ketene-derived products in the photolysis of certain tricyclic ketones incorporating the 2-norbornanone system results from conformational constraints in the biradical formed by α-cleavage that facilitate the hydrogen abstraction process leading to ketene formation.
J. C. L. Tam and P. Yates, J. Chem. Soc., Chem. Commun., 1975, 739 DOI: 10.1039/C39750000739
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