Evidence is presented that the substitution by triphenyl phosphite, in decalin or cyclohexane of one triphenylphosphine in the complex [Mn(CO)4PPh3]2 occurs via initial reversible homolytic fission of the Mn–Mn bond followed by an associative interchange reaction of triphenyl phosphite with the Mn(CO)4PPh3 radical.
J. P. Fawcett, R. A. Jackson and A. Poë, J. Chem. Soc., Chem. Commun., 1975, 733 DOI: 10.1039/C39750000733
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