Issue 17, 1975

A platinum-promoted ring-opening reaction of hexakistrifluoromethylbenzene involving carbon–carbon bond cleavage; crystal and molecular structure of bis(t-butyl isocyanide)platinacyclohepta-cis-2,cis-4,cis-6-triene

Abstract

Reaction of hexakis(trifluoromethyl)benzene with triangulo-[Pt3(ButNC)6] or trans-stilbenebis(trimethyl-phosphine)platinum affords the metallacyclohepta-cis,cis,-cis-trienes [[grphic omitted](CF3)L2]; the bis(t-butylisocyanide) complex has been identified structurally by X-ray crystallography.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1975, 723-724

A platinum-promoted ring-opening reaction of hexakistrifluoromethylbenzene involving carbon–carbon bond cleavage; crystal and molecular structure of bis(t-butyl isocyanide)platinacyclohepta-cis-2,cis-4,cis-6-triene

J. Browning, M. Green, A. Laguna, L. E. Smart, J. L. Spencer and F. G. A. Stone, J. Chem. Soc., Chem. Commun., 1975, 723 DOI: 10.1039/C39750000723

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