Issue 17, 1975
From the journal:

Journal of the Chemical Society, Chemical Communications

Formation of carbyne-like ligands by the protonation of isonitriles ligating electron-rich metal centres; X-ray structure of trans-[Mo(CNMe)2(Ph2PCH2CH2PPh2)]

Joseph Chatt,   Armando J. L. Pombeiro,   Raymond L. Richards,   Geoffrey H. D. Royston,   Kenneth W. Muir  and  Robert Walker  

Abstract

The compounds trans-[M(CNR)2(dpe)2](M = Mo or W; R = Me, But or aryl; dpe = Ph2PCH2CH2-PPh2) have been prepared, and they can be protonated at one or both nitrogen atoms giving carbyne-like ligands, but alkylated at only one; X-ray structure analysis shows that the CNMe angle in trans-[Mo(CNMe)2(dpe)2] is 156(1)°.

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Article information

DOI
https://doi.org/10.1039/C39750000708
Article type
Paper

J. Chem. Soc., Chem. Commun., 1975, 708-709

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Formation of carbyne-like ligands by the protonation of isonitriles ligating electron-rich metal centres; X-ray structure of trans-[Mo(CNMe)2(Ph2PCH2CH2PPh2)]

J. Chatt, A. J. L. Pombeiro, R. L. Richards, G. H. D. Royston, K. W. Muir and R. Walker, J. Chem. Soc., Chem. Commun., 1975, 708 DOI: 10.1039/C39750000708

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