Activation parameters for the solvolysis of t-butyl chloride in water–ethanol mixtures. Glycine as a transition state model
Abstract
Variations in ΔG‡, ΔH‡, and ΔS‡ for the solvolysis of t-butyl chloride in water–ethanol mixtures are accounted for when glycine is used as a transition state model, provided that differences in molar volumes are taken into account.