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Perhydroquinacene, a building unit of the unknown hydrocarbon dodecahedrane, has a gas-phase enthalpy of formation of –102·39 ± 3·60 kJ mol–1, suggesting that the strain energy of dodecahedrane should be considerably lower than that predicted by the Allinger empirical force field method.
T. Clark, T. McO. Knox, H. Mackle and M. A. McKervey, J. Chem. Soc., Chem. Commun., 1975, 666 DOI: 10.1039/C39750000666
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