New synthetic route to 2′,3′-unsaturated pyranosyl thymine from the corresponding O2,2′-cyclonucleoside
Abstract
Treatment of the O2,2′-cyclonucleoside (3) with NaI–Zn gives the corresponding 2′,3′-unsaturated nucleoside (4) in fair yield.
Treatment of the O2,2′-cyclonucleoside (3) with NaI–Zn gives the corresponding 2′,3′-unsaturated nucleoside (4) in fair yield.
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T. Yamazaki, H. Shiraishi, K. Matsuda, H. Sugiyama, S. Seto and N. Yamaoka, J. Chem. Soc., Chem. Commun., 1975, 518 DOI: 10.1039/C39750000518
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