Poly(vinyl chloride) was found to degrade thermally via a dual mechanism—the unimolecular elimination of hydrogen chloride, and a radical chain process, the latter being the predominant pathway at 194 °C.
K. P. Nolan and J. S. Shapiro, J. Chem. Soc., Chem. Commun., 1975, 490 DOI: 10.1039/C39750000490
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