Irradiation of vitamin B12 coenzyme or ethylcobalamin (LCoIII–R) in the presence of a nitroso compound R′NO (R′= But or 2,3,5,6-Me4C6H) under anaerobic conditions in H2O (R′= But), Me2SO, or PhOH–CHCl3, affords the spin-trapped nitroxide R′N(Ȯ)R.
K. N. Joblin, A. W. Johnson, M. F. Lappert and B. K. Nicholson, J. Chem. Soc., Chem. Commun., 1975, 441 DOI: 10.1039/C39750000441
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