Issue 11, 1975

Unusual bonding patterns in halogen-substituted η5-cyclopentadienyl metal derivatives. The crystal and molecular structure of η5-pentachlorocyclo-pentadienylcyclo-octadienerhodium

Abstract

Localized bonding has been observed in the η5-C5Cl5 ring of the title compound which suggests appreciable contribution from a bonding model where the ring is bonded to the metal by two olefin π-bonds and one σ-alkyl bond.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1975, 403-404

Unusual bonding patterns in halogen-substituted η5-cyclopentadienyl metal derivatives. The crystal and molecular structure of η5-pentachlorocyclo-pentadienylcyclo-octadienerhodium

V. W. Day, K. J. Reimer and A. Shaver, J. Chem. Soc., Chem. Commun., 1975, 403 DOI: 10.1039/C39750000403

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