Reaction of B9H12– and Ni(C5H5)2 with Na amalgam gives the metalloborane [(η5-C5H5)-2-Ni(η5-B9H9)]– which is quantitatively converted to a second isomer [(η5-C5H5)-1-Ni(η4-B9H9)]– by thermal isotion.
R. N. Leyden and M. F. Hawthorne, J. Chem. Soc., Chem. Commun., 1975, 310 DOI: 10.1039/C39750000310
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