Stereochemical studies on cyclohexane-1,2-diols and scavenger experiments on dioxan indicate that the radiation-induced hydrogen exchange at C-H bonds involves the reaction sequence: RH[graphic omitted] R·[graphic omitted]R–[graphic omitted]RT, the first two steps of which occur in spur regions.
V. Gold and M. E. McAdam, J. Chem. Soc., Chem. Commun., 1975, 228 DOI: 10.1039/C39750000228
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