A direct current applied across the liquid-liquid interphase of a heterogeneous, unreactive Cu2+–[V(CO)6]– redox system, causes deposition of a copper layer at the interface.
M. Guainazzi, G. Silvestri and G. Serravalle, J. Chem. Soc., Chem. Commun., 1975, 200 DOI: 10.1039/C39750000200
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