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The crystal structures of the three title compounds have been determined; the dramatic differences in their M–N–C bond angles suggest that Si is subsantially involved in pπ–dπ bonding, that Ge is partially involved, and that Sn shows no pπ–dπ bonding.
N. W. Alcock, M. Pierce-Butler, G. R. Willey and K. Wade, J. Chem. Soc., Chem. Commun., 1975, 183 DOI: 10.1039/C39750000183
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