Temperature effects in photoelectron spectroscopy can be used to study electronic structure variation between conformational isomers; this is illustrated by reference to tetramethyl-diphosphine and some disubstituted ethanes.
D. L. Ames and D. W. Turner, J. Chem. Soc., Chem. Commun., 1975, 179 DOI: 10.1039/C39750000179
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