14  N–31P, 15N–15P, and 31P–31P coupling constants from the 31P nuclear magnetic resonance spectra of square planar platinum(II) and palladium(II) thiocyanate complexes

Arthur J. Carty; Stephen E. Jacobson

doi:10.1039/C39750000175

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¹⁴N–³¹P, ¹⁵N–¹⁵P, and ³¹P–³¹P coupling constants from the ³¹P nuclear magnetic resonance spectra of square planar platinum(II) and palladium(II) thiocyanate complexes

Arthur J. Carty and Stephen E. Jacobson

Abstract

The ³¹P n.m.r. spectra of cis-PtX₂[P(OPh)₃]₂(X = CNS, C¹⁵NS) show the independent existence of dithiocyanato, diisothiocyanato and mixed linkage isomers in solution, and the appearance of distinct resolvable ³¹P–³¹P, ¹⁴N–³¹P and ¹⁵N–³¹P coupling in the spectra of the mixed species suggests a means of measuring these couplings in co-ordination complexes.

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DOI: https://doi.org/10.1039/C39750000175
Article type: Paper

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J. Chem. Soc., Chem. Commun., 1975, 175-176

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¹⁴ N–³¹P, ¹⁵N–¹⁵P, and ³¹P–³¹P coupling constants from the ³¹P nuclear magnetic resonance spectra of square planar platinum(II) and palladium(II) thiocyanate complexes

A. J. Carty and S. E. Jacobson, J. Chem. Soc., Chem. Commun., 1975, 175 DOI: 10.1039/C39750000175

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Journal of the Chemical Society, Chemical Communications