The regioselectivity and stereoselectivity of palladium π-allyl chloride complex formation from steroidal olefins was apparently controlled by steric effects, and both cholest-4-ene and cholest-5-ene gave diastereoisomeric complexes; two of the complexes were reduced to olefins by lithium aluminium hydride stereo-specifically with retention of configuration.
D. N. Jones and S. D. Knox, J. Chem. Soc., Chem. Commun., 1975, 165 DOI: 10.1039/C39750000165
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