Evaporated gold films exhibit extremely high catalytic activity at 195 K for the hydrogen exchange reaction between MeSiH3 and MeSiD3; only protium and deuterium bonded to silicon participate in the exchange and the activity is diminished at higher temperatures owing to poisoning of the surface by products of methylsilane chemisorption.
D. I. Bradshaw, R. B. Moyes and P. B. Wells, J. Chem. Soc., Chem. Commun., 1975, 137 DOI: 10.1039/C39750000137
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