Issue 4, 1975

Cycloaddition of t-butylcyanoketen to racemic and optically active 1,3-diphenylallene

Abstract

X-Ray studies show the major adduct from t-butylcyanoketen and racemic 1,3-diphenylallene to be (1), and the only other adduct is shown to have structure (2); use of optically active allene shows that both are formed to some extent via a chiral transition state.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1975, 132-133

Cycloaddition of t-butylcyanoketen to racemic and optically active 1,3-diphenylallene

H. A. Bampfield, P. R. Brook and W. S. McDonald, J. Chem. Soc., Chem. Commun., 1975, 132 DOI: 10.1039/C39750000132

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