Concentration dependence of the rate constants for 2 + 2 cycloadditions of tetracyanoethylene
Abstract
The dependence of the second-order rate constants for the 2 + 2 cycloaddition of tetracyanoethylene to dihydropyran on the molar concentration in various solvents is due to a change in the polarity of the medium rather than to variation in charge-transfer complex concentration.
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