Issue 2, 1975

Concentration dependence of the rate constants for 2 + 2 cycloadditions of tetracyanoethylene

Abstract

The dependence of the second-order rate constants for the 2 + 2 cycloaddition of tetracyanoethylene to dihydropyran on the molar concentration in various solvents is due to a change in the polarity of the medium rather than to variation in charge-transfer complex concentration.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1975, 59-60

Concentration dependence of the rate constants for 2 + 2 cycloadditions of tetracyanoethylene

R. Huisgen and R. Schug, J. Chem. Soc., Chem. Commun., 1975, 59 DOI: 10.1039/C39750000059

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