The mechanism of aromatic iodination proposed previously has been confirmed by a study of the reactions of substituted thiophens. For 2-phenylthiophen the kinetic hydrogen isotope effect depends upon the substrate concentration, which is consistent with the reaction scheme.
A. R. Butler and A. P. Sanderson, J. Chem. Soc., Perkin Trans. 2, 1974, 1214 DOI: 10.1039/P29740001214
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