Equilibrium and kinetic processes in acyclic, cyclic, and polycyclic tetra-alkyltetrazines are discussed with reference both to new and to literature data. A consistent overall picture is presented in terms of ‘passing’ and ‘non-passing’ inversion processes which differ in the magnitude of steric hindrance in the transition state.
R. A. Y. Jones, A. R. Katritzky, K. A. F. Record and R. Scattergood, J. Chem. Soc., Perkin Trans. 2, 1974, 406 DOI: 10.1039/P29740000406
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