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Issue 0, 1974
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Pre-melting transitions in caged hydrocarbons, a general theory of disorder in plastic crystals

Abstract

The results of differential scanning calorimetry studies on caged hydrocarbons have been used, with existing data, to propose a new interpretation of orientational disorder in plastic crystals. New empirical relationships are reported between the entropy of transition, plastic crystal range and molecular shape.

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Article information


J. Chem. Soc., Faraday Trans. 1, 1974,70, 1279-1291
Article type
Paper

Pre-melting transitions in caged hydrocarbons, a general theory of disorder in plastic crystals

T. Clark, M. A. McKervey, H. Mackle and J. J. Rooney, J. Chem. Soc., Faraday Trans. 1, 1974, 70, 1279
DOI: 10.1039/F19747001279

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