Standard enthalpies of formation of XeF2,MF5, XeF2,2MF5(M = Sb, Ta, or Nb), and 2XeF2,M F5(M = Sb or Ta) have been estimated from their heats of alkaline hydrolyses. The ionicity order of these compounds (Sb > Ta > Nb) adduced from vibrational spectroscopy is confirmed by the thermochemical results.
J. Burgess, B. Frlec and J. H. Holloway, J. Chem. Soc., Dalton Trans., 1974, 1740 DOI: 10.1039/DT9740001740
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