SCHEDULED MAINTENANCE
The first isolated niobium pentamethoxide complexes Nb(OMe)5,L (I; L = pyridine, γ-picoline, morpholine, hydrazine, trimethylamine oxide, and hexamethylphosphoramide) are reported, together with Ta(OMe)5,N2H4. N.m.r. and i.r. spectra are discussed in terms of formation of octahedral six-co-ordinate niobium complexes. In these complexes hydrazine behaves as a unidentate ligand.
L. G. Hubert-Pfalzgraf and J. G. Riess, J. Chem. Soc., Dalton Trans., 1974, 585 DOI: 10.1039/DT9740000585
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