Issue 4, 1974
From the journal:

Journal of the Chemical Society, Dalton Transactions

Methylseleno-derivatives of Group IV. Part II. Hydrides

Geoffrey K. Barker,   John E. Drake  and  Raymond T. Hemmings  

Abstract

The following methylseleno-derivatives of Group IV hydrides, SiH3·SeMe, SiH2(SeMe)2, MeSiH2·SeMe, GeH3·SeMe, MeGeH2·SeMe, and Me2GeH·SeMe have been fully characterised by cleavage reactions and 1H n.m.r. and vibrational spectroscopy. The silanes were prepared from lithium tetramethylselenoaluminate and the germanes by exchange reactions involving methylseleno(trimethyl)silane. A full assignment of the i.r. and Raman spectra, supported by normal co-ordinate analyses, is presented for MH3SeMe.

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Article information

DOI
https://doi.org/10.1039/DT9740000450
Article type
Paper

J. Chem. Soc., Dalton Trans., 1974, 450-455

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Methylseleno-derivatives of Group IV. Part II. Hydrides

G. K. Barker, J. E. Drake and R. T. Hemmings, J. Chem. Soc., Dalton Trans., 1974, 450 DOI: 10.1039/DT9740000450

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