SCHEDULED MAINTENANCE
Prolonged u.v. photolysis of the matrix isolated complex [Fe(CO)5] results in formation of the fragment [Fe(CO)3]. Isotopic substitution indicates a pyramidal C3v structure. Possible reasons for this structure are discussed. Further u.v. photolysis produces Fe(CO)x species (x < 3).
M. Poliakoff, J. Chem. Soc., Dalton Trans., 1974, 210 DOI: 10.1039/DT9740000210
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