Issue 17, 1974
From the journal:

Journal of the Chemical Society, Chemical Communications

Preparation of dimethylbis(diphenylphosphinoethane)iron(II) and its decomposition pathways involving the formation of carbenoid intermediates

Takao Ikariya  and  Akio Yamamoto  

Abstract

Reaction of Fe(acac)3, Me2AIOEt, and Ph2– PCH2CH2PPh2(dpe) gives a new methyliron complex, FeMe2(dpe)2 which on thermal decomposition and treatment with CH2Cl2 liberates ethylene, the formation of which suggests the intermediacy of carbenoid complexes.

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Article information

DOI
https://doi.org/10.1039/C3974000720A
Article type
Paper

J. Chem. Soc., Chem. Commun., 1974, 720a-720a

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Preparation of dimethylbis(diphenylphosphinoethane)iron(II) and its decomposition pathways involving the formation of carbenoid intermediates

T. Ikariya and A. Yamamoto, J. Chem. Soc., Chem. Commun., 1974, 720a DOI: 10.1039/C3974000720A

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