Issue 23, 1974
From the journal:

Journal of the Chemical Society, Chemical Communications

Sign and magnitude of 1K(Sn–C) in trimethylstannyl-lithium: the first example of a negative reduced nuclear spin–spin coupling constant between two directly bound Group IV elements

John D. Kennedy  and  William McFarlane  

Abstract

The electron-mediated reduced nuclear spin–spin coupling constants 1K(Sn–C) and 2K(Sn–H) are negative and positive respectively in trimethylstannyl-lithium; this is attributed to the presence of a lone pair of electorns on the tin atom.

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Article information

DOI
https://doi.org/10.1039/C39740000983
Article type
Paper

J. Chem. Soc., Chem. Commun., 1974, 983-984

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Sign and magnitude of 1K(Sn–C) in trimethylstannyl-lithium: the first example of a negative reduced nuclear spin–spin coupling constant between two directly bound Group IV elements

J. D. Kennedy and W. McFarlane, J. Chem. Soc., Chem. Commun., 1974, 983 DOI: 10.1039/C39740000983

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