Furan is shown to undergo a novel photochemical 2,5-, 1′,4′-cycloaddition to benzene; the product readily undergoes reversible thermal, or irreversible photochemical Cope rearrangement to a 2,3-, 1′,2′-isomer.
J. Berridge, D. Bryce-Smith and A. Gilbert, J. Chem. Soc., Chem. Commun., 1974, 964 DOI: 10.1039/C39740000964
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